Volume 419
Main Index

Issues 1-2, Pages 1-276 (12 November 1991)

Oxidation of organometallic compounds with polychalcogenides: preparation and structure of [(Me5C5)Mo(S4)(S2CO)]− containing a dithiocarbonate ligand Pages C10-C13 Samantha L. Gales, William T. Pennington, Joseph W. Kolis

Regioselective access to tricarbonyliron complexes: controlled preparation and reactions of trifluoromethyl-substituted complexes Pages C14-C17 G. Richard Stephenson, Philip W. Howard, Stephen C. Taylor

A handy preparation of bis(trimethylsilyl)methylamine Pages C1-C4 Jean-Paul Picard, Stéphane Grelier, Jacques Dunoquès, Jesus-Maria Aizpuna, Claudio Palomo

Successive formation of enaminoketene and arenetricarbonyl nitrogen ylid chromium complexes during intramolecular alkyne insertions into aminocarbene complexes Pages C5-C9 E. Chelain, A. Parlier, H. Rudler, J. C. Daran and, J. Vaissermann

Author index Page C21

Direct observation of ion pair formation in dichloromethane solution and the crystal structure of [(η5-C5Me5)Fe(CO)3][BF4] Pages C18-C20 Patrick McArdle, David MacHale, Desmond Cunningham, A. R. Manning

Metalation reactions : XV. Regioselective metalation of (alkylthio)fluorobenzenes Pages 1-8 S. Cabiddu, C. Fattuoni, C. Floris, G. Gelli, S. Melis

Aminosilylation of heterocumulenes and the intramolecular decomposition of their silyl-functionalized adducts Pages 9-26 R. J. P. Corriu, Gérard F. Lanneau, V. D. Mehta

HeI and HeII photoelectron spectroscopic investigation of subsituent effects in aminosilanes Pages 27-42 Attila Nagy, Jennifer C. Green, Laszlo Szepes, Laszlo Zanathy

Öffnung von Clustergerüsten: erhöhung der Gerüstelektronenzahl von Clustern durch Aminosubstituenten Pages 43-55 B. Eber, G. Huttner, Chr. Emmerich, J. C. Daran, B. Heim and, Y. Jeannin

A new spirogermole : its synthesis, and some aspects of its reactivity Pages 57-62 Jean-Dominique Andriamizaka, Claude Couret, Jean Escudié, André Laporterie and, Georges Manuel, Manfred Regitz

Extrusion of selenium and tellurium atoms from selenophene and tellurophene by reaction with trinuclear iron, ruthenium, and osmium clusters: crystal structures of [Os6(μ-H)(μ3-Se)(μ4-C4H3)(CO)20] and of [Ru4(μ3-Se)μ-C4H4)(CO)11] Pages 63-75 Alejandro J. Arce, Ruben Machado, Carlos Rivas, Ysaura De Sanctis, Antony J. Deeming

Monopentamethylcyclopentadienyltitanium(IV) halo-alkoxides, alkyl-alkoxides and acetylacetonates Pages 77-84 Pilar Gómez-Sal, Avelino Martín, Miguel Mena, Pascual Royo, Ricardo Serrano

Zweikernige Pentamethylcyclopentadienyl-Vanadium-Komplexe mit Tellurbrücken. Anwendung der 51V NMR-Spektroskopie zur Identifizierung neuer Vanadium-Verbindungen mit unterschiedlichen Chalkogenen im Brückensystem Pages 85-100 Max Herberhold, Matthias Schrepfermann

Photochemistry of (η5-cyclopentadienyl)-tricarbonylmethylchromium in gas matrices and polymer films at 12—298 K: infrared spectroscopic evidence for reversible carbon monoxide ejection and α-H elimination from the methyl group Pages 101-112 Richard H. Hooker, Khalil A. Mahmoud, Antony J. Rest, Helmut G. Alt

Photolysis of Group VI metal carbonyls, (η6-C6H6)Cr(CO)3, (η5-C5H5)Mn(CO)3, (η5-CH3C5H4)Mn(CO)3 and (η5-C5H5)Re(CO)3 in Nujol at 77 K Pages 113-126 Thomas E. Bitterwolf, Kimberly A. Lott, Antony J. Rest and, Joëlle Mascetti

Synthesis, characterization, and reactivity of cyclopentadienyltrichloromolybdenum(IV). X-Ray structure of CpMoCl3[P(OCH2)3CEt]2 (Cp = η5-C5H5) Pages 127-136 Rinaldo Poli, Malcolm A. Kelland

Alkyne, cyclobutadiene and cyclopentadienone complexes of molybdenum and tungsten Pages 137-149 Jack L. Davidson

Matrix-isolation studies of intermediates in the photochemical reaction of W(CO)6 with CCl4 Pages 151-162 T. Szymaska-Buzar, A. J. Downs, T. M. Greene, M. A. K. Wood

Reactions of the unsaturated dihydrides [Mn2(μ-H)2(CO)6(μ-L2)](L2 = (EtO)2POP(OEt)2, Ph2PCH2PPh2) with phosphines containing P---H bonds Pages 163-170 Remedios Carreño, Victor Riera, Miguel A. Ruiz

Silylphosphinites and their complexation to manganese. Crystal structure of cis-MnBr(Br(CO)4[P(4-CH3C6H4)2OSiMe3] Pages 171-180 Kim M. Cooke, Terence P. Kee, Anna L. Langton, Mark Thornton-Pett

Preparation, structure, and reaction of the tricarbonyliron complex of tricyclo[5.3.1.04,9]undeca-2,5-diene, a strongly homo-conjugated nonparallel 1,4-diene Pages 181-191 Nozomu Sakai, Kazushi Mashima, Hidemasa Takaya, Ryohei Yamaguchi and, Sinpei Kozima

The disordered crystal structure of [RuCo3H(CO)12] Pages 193-203 Jouni Pursiainen, Pipsa Hirva, Tapani A. Pakkanen

Alkylcobalt carbonyls : XI. Ligand-assisted carbonylation—decarbonylation reactions of alkylcobalt carbonyls Pages 205-217 Judit Somlyai-Haáz, Ferenc Haász, Vilmos Galamb, Adriano Benedetti, Claudia Zucchi, Gyula Pályi, Thomas Krümmling, Berit Happ and, Tamás Bartik

Dimethylsulfide derivatives of [Rh6(CO)16]. Crystal structures of [Rh6(CO)15(SMe2)] and [Rh6(CO)12(SMe2)4] Pages 219-232 Sirpa Rossi, Kauko Kallinen, Jouni Pursiainen, Tuula T. Pakkanen, Tapani A. Pakkanen

Spectroscopic and electrochemical properties of the isomeric bidiazine complexes [(C5Me5)CiRh(bdz)]+ and (C5Me5)Rh(bdz) and their relevance to the catalysis of the 2 H+ → H2 reaction by 2,2′-bipyridine analogues Pages 233-243 Monika Ladwig, Wolfgang Kaim

Preparation of alkyl-Fp [Fp = (C5H5)Fe(CO)2] complexes via organometallic reagents: reactions of RMgX and RLi with Fp-I and Fp-THF+BF4- Pages 245-249 Hong-ju Li, Mark M. Turnbull

Oxidative carbonylation of aliphatic amines catalysed by nickel-complexes Pages 251-258 Potenzo Giannoccaro, Cosimo Francesco Nobile, Pietro Mastrorilli, Nicoletta Ravasio

Synthesis of σ-alkyl diketonato and monothio ß-diketonato complexes of platinum(II) and palladium(II) Pages 259-268 Hong Jin, Kingsley J. Cavell

Crystal structure and further applications of the chiral derivatising agent η2-ethene platinum-DIOP Pages 269-276 Russell Fulwood, David Parker, George Ferguson, Branko Kaltner

Issue 3, Pages 277-415 (1991)

The synthesis of mono- and di-methyl gallium tetraaza macrocycles [MeGa(C22H22N4)] and [Me2Ga(C22H23N4)] and the molecular structure of the dimethyl gallium derivative Pages C23-C26 N. W. Alcock, N. C. Blacker, M. G. H. Wallbridge, J. Barker

Subject index Pages C29-C33

Author index Pages C27-C28

Synthesis and crystal structure of Me2SnCl2·(2-MeOC6H4N=CHC5H4N-2) Pages 277-282 T. K. Chattopadhyay, A. K. Kumar, A. Roy, A. S. Batsanov, E. B. Shamuratov, Yu. T. Struchkov

High metal coordination numbers in group 15 organometallics: crystal structures of triphenylbismuthbis(trifluoroacetate) and triphenylantimonybis(trifluoroacetate) Pages 283-291 George Ferguson, Branko Kaitner, Christopher Glidewell and, Sylvia Smith

Preparation and molecular structure of methylbis(t-butyl-cyclopentadienyl)neodymium and -gadolinium Pages 293-298 Qi Shen, Yanxiang Cheng, Yonghua lin

Coordinationally oversaturated metallocene derivatives. The crystal and molecular structure of [(η5-C5H5)2Sm(μ3-H)]2[(μ2-H)2AlH · N(C2H5)3]2 and [(η5-C5H4tBu)2Sm]2-(μ2-H)μ-[(μ3-H)2Al(μ2-H)2 · Me2NC2H4NMe2] complexes Pages 299-310 V. K. Belsky, Yu. K. Gun'ko, B. M. Bulychev, G. L. Soloveichik

Homo- and heteronuclear hydrido lutetiecene complexes with bulky 1,3-di(tert-butyl)cyclopentadienyl (C5H3tBu2) ligands. The molecular structure of [(tBu2C5H3)LuH]4[AlH4·Et2O]2[AlH4]2 Pages 311-324 S. Ya. Knjazhanski, E. B. Lobkovsky, B. M. Bulychev, V. K. Belsky, G. L. Soloveichik

Syntheses and spectra of [η5-(C5H4COOCH3)]Cr(NO)2L (L = Cl, I, CH3) and crystal structures of [η5-(C5H4COOCH3)]Cr(NO)2L (L = Cl, I) Pages 325-335 Yu-Pin Wang, Yuh-Huei Yang, Sue-Lein Wang and, Fen-Ling Liao

Preparation of tricarbonyl(benzene)chromium and ferrocene containing unsaturated amides and nitriles Pages 337-340 Jiling Huang, Hong-Xia Jiang, Yao-Zeng Huang

Bromination and alkylation of tricarbonyl(η1,η2-but-3-en-1-yl)iron(O) anion complexes Pages 341-355 Ming-Chang P. Yeh, Chong-Chen Hwu

Cyclopentadienyliron-mediated introduction of functionalized alkyl or alkynyl groups to arenes in an addition—demetallation sequence Pages 357-373 Ronald G. Sutherland, Chunhao Zhang, Adam Piórko

A comparison of the energy barriers to bridge reversal in trisulphur-and triselenium-bridged [3] metallocenophanes Pages 375-382 Edward W. Abel, Nicholas J. Long, Keith G. Orrell, Anthony G. Osborne, Vladimirik

Some chiral alkyne-cobalt complexes Pages 383-389 John A. Dunn, Peter L. Pauson

Substitution of CO by picolines and amines in RhCl(CO)(PR3)2. Synthesis and crystal structure of cis-RhCl(3-pic){P(OPh)3}2 Pages 391-398 A. M. Trzeciak, J. J. Ziólkowski, T. Lis

Fast olefin site interchange of cycloocta-1,5-diene in a RhI square planar derivative Pages 399-402 E. Rotondo, G. Battaglia, C. G. Arena, F. Faraone

Synthesis of a new family of water-soluble tertiary phosphine ligands and of their rhodium(I) complexes; olefin hydrogenation in aqueous and biphasic media Pages 403-415 Eric Ranaud, Robert B. Russell, Suzanne Fortier, Stephen J. Brown, Michael C. Baird